包装 价格 库存 - 促销价
100mL??? RMB???103
500mL??? RMB???261
1L?????? RMB???421
Diisobutylaluminum hydride
二异丁基氢化铝

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  • Mol. Formula: [(CH3)2CHCH2]2AlH
  • Mol. Weight: 142.22
  • Density: 0.848
  • TSCA: Yes
  • Flash Point: -23°(-10°F)
  • Boiling Point: 110
  • Melting Point: -70
  • Solubility: 剧烈反应
  • Stability: 易吸潮
Chemical NameDiisobutylaluminum hydride
CAS Number1191-15-7
EC Number214-729-9
Beilstein Registry Number4123663
MDL NumberMFCD00008928
Synonym
  • 氢化二异丁基铝
  • DIBAL-H
  • Al-Alchili
  • 二异丁基氢化铝, 25%甲苯溶液
  • Aluminum, diisobutylhydro-
  • DIISOBUTYLALUMINUM HYDRIDE
  • Bis(isobutyl)hydroaluminum
  • 二异丁基氢化铝, 20% (CA 1M) SOLN. IN TOLUENE
  • 氢化二异丁基铝
  • hydrobis(2-methylpropyl)-aluminu
  • hydrobis(2-methylpropyl)-Aluminum
  • DIBAL-H;DIBAL
  • Aluminum, hydrodiisobutyl-
  • DIISOBUTYLALUMINIUM HYDRIDE
  • Aluminum, hydrobis(2-methylpropyl)-
  • DIBAH
  • 二异丁基氢化铝 溶液
  • Diisobutylhydroaluminum
  • DIBAL-H DIBAL
  • hydrobis(2-methylpropyl)aluminum
  • 二异丁基氢化铝
  • DI-I-BUTYLALUMINUM HYDRIDE
  • Diisobutylaluminum
  • 二异丁基氢化铝, 1M SOLUTION IN HEXANE
    PubChem Substance ID24852856
    Chemical Name Translation二异丁基氢化铝
    Wiswesser Line Notation1Y1&1-AL-H1Y1&1
    Signal word
      GHS Symbol
      WGK Germany2
      Safety Statements
      • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
      • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
      • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
      • S29 Do not empty into drains 不要排入下水道;
      • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
      • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
      • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R48/20
        • R17 Spontaneously flammable in air 在空气中能够自燃
        • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
        • R35 Causes severe burns 会导致严重灼伤
        • R34 Causes burns 会导致灼伤
        • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
        • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
        • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
        • R19 May form explosive peroxides 可能生成易爆的过氧化物质
        • R37 Irritating to respiratory system 刺激呼吸道
        • R14 Reacts violently with water 遇水会猛烈反应
        • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
        • R51/53
          Precautionary statements
            Hazard statements
            • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
            • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
            • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
            • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
            • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
            • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
            • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
            • H335 May cause respiratory irritation 可能导致呼吸道刺激
            • H351 Suspected of causing cancer 怀疑致癌
            • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
            • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
            • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
            • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
            • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
              Personal Protective Equipment
              • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
              • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
                Packing GroupI
                UN Number
                  Storage condition
                  • Moisture Sensitive
                  • 易吸潮,密封充氩保存
                  • Air & Moisture Sensitive
                  • 充氩保存
                  • 2-8°C
                    RTECSBD0710000
                    Hazard Codes
                    • F,C
                      Hazard Class4.3
                      TYPE OF TEST            : LCLo - Lowest published lethal concentration
                      ROUTE OF EXPOSURE       : Inhalation
                      SPECIES OBSERVED        : Rodent - guinea pig
                      DOSE/DURATION           : 70 gm/m3/1H
                      TOXIC EFFECTS :
                         Lungs, Thorax, or Respiration - other changes
                      REFERENCE :
                         MELAAD Medicina del Lavoro.  Industrial Medicine.  (Via S. Barnaba, 8, 20122
                         Milan, Italy) V.16-    1925-  Volume(issue)/page/year: 57,188,1966

                    • ⑴.无色液体,高度易燃。引起严重灼伤。吞食可能造成肺部损伤。蒸汽可能引起困倦和眩晕。 ⑵.主要用作精细化学品的还原剂和氢铝化剂。 ⑶.具有强烈的吸湿性,对空气和湿气敏感,遇水会发生激烈反应放出氢气。 ⑷.四氢呋喃不适宜作溶剂,因为两者反应生成配位化合物。二异丁基氢化铝是一种新型金属有机化合物,可使酮、羧酸、酯选择性还原成相应的醛或者醇。
                    • Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.
                    • Merck: 14,10425
                    • Reduces chiral ɑ-silyloxy esters to the corresponding enantiomerically-pure hydroxy aldehydes: J. Chem. Soc., Chem. Commun., 2475 (1995).
                    • Merck: 14,10425 Beilstein:4(4)4400
                    • 部分产品数据参考 LabNovo , 请谨慎使用并以实际实验测量值为准。